Comparison of the results with DFT calculations of the electronic structure allows the properties of the diethynylaryl bridged, bimetallic complexes to be rationalised in terms of a significant contribution of the diethynylaryl bridging ligand to the SOMO. The electronic properties of the 1,12 diethynyl carborane bridged species 1,12 (_2)(u CC CB(_10)H(_10)C CC), and the related mononuclear complex Ru(CC CB(_10)H(_10)H)(dppe)Cp, are assessed by a combination of electrochemical and spectroscopic techniques. The results allow a comparison of the ‘three dimensional’ aromatic spacer l,12 C(_2)BH(_10) with the phenylene analogue.
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